Course Content
Introduction to Environmental Chemistry
Environmental chemistry is the study of the chemical and biochemical phenomena that occur in nature. It involves the understanding of how the uncontaminated environment works, and which naturally occurring chemicals are present, in what concentrations and with what effects. Environmental chemistry; is the study of sources, reactions, transport, effects and fate of chemical species in water, soil and air environment as well as their effects on human health and natural environment
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Origin of the solar System
Cosmology; is the branch of astronomy involving the study of the of the universe and the solar system. Cosmo-chemistry ;( chemical cosmology); is the study of chemical composition of the matter in the universe and the process that led to those compositions The solar system is made up of the sun (a star) with nine planets orbiting around it. These planets together with all the other heavenly bodies moving around or between individual planet form members of the solar system. Other heavenly body include; asteroids, comets, meteors, meteorites and satellites such as moon. The solar system does not include other stars .
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Solutions
Solutions are defined as homogeneous mixtures that are mixed so thoroughly that neither component can be observed independently of the other. The major component of the solution is called solvent, and the minor component(s) are called solute.
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Chemical Equilibria
Chemical equilibrium in the environment refers to the state where the rates of forward and reverse reactions of a chemical reaction reach a balance. In this state, the concentrations of reactants and products remain constant over time, although the reactions continue to occur.
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Phase Interactions
Phase interactions in solutions refer to the behavior and changes that occur when two or more substances (solutes and solvents) mix together to form a homogeneous mixture. These interactions are related to the different phases of matter, such as solids, liquids, and gases, and how they interact and transform during the process of solution formation.
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Colligative Properties of Solutions
COLLIGATIVE PROPERTIES OF SOLUTIONS Colligative properties are physical properties of solutions that depend on the concentration of solute particles, rather than the specific identity of the solute. The four colligative properties that can be exhibited by a solution are: 1.Boiling point elevation 2.Freezing point depression 3.Relative lowering of vapour pressure 4.Osmotic pressure
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Introduction To Organic Chemistry
Organic chemistry is the study of carbon containing compounds and their properties. This includes the great majority of chemical compounds on the planet, but some substances such as carbonates and oxides of carbon are considered to be inorganic substances even though they contain carbon.
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Air Quality and Pollution
Air Quality and Pollution
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Introduction To Environmental Chemistry
About Lesson

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Salinity of Soil

Soil salinity refers to the concentration of soluble salts in the soil, specifically the amount of dissolved salts in the soil water or soil solution. It is a measure of the salt content present in the soil and is typically expressed in terms of electrical conductivity (EC) or total dissolved solids (TDS).

Excessive soil salinity can have negative impacts on plant growth and agricultural productivity. When salt concentration is high in the soil, it creates an osmotic imbalance, making it more difficult for plants to extract water from the soil. This can lead to water stress, reduced nutrient uptake, and impaired plant growth. In severe cases, high soil salinity can result in plant wilting, leaf burn, and even plant death.

Soil salinity can occur naturally in certain regions, such as coastal areas, arid and semiarid regions, and in soils derived from saline parent materials. Natural causes of soil salinity include the accumulation of salts through weathering of rocks, mineral deposits, and saltwater intrusion into groundwater. Additionally, human activities can contribute to soil salinity. Common causes include improper irrigation practices, excessive use of fertilizers containing salts, and poor drainage systems that lead to waterlogging and salt accumulation.

Measuring soil salinity is typically done using electrical conductivity (EC) measurements. EC is a measure of the ability of the soil solution to conduct an electrical current and is directly related to the concentration of dissolved salts. EC is commonly expressed in units of deciSiemens per meter (dS/m) or milliSiemens per centimeter (mS/cm). Soil samples are usually taken and analyzed in a laboratory, or portable conductivity meters can be used for on-site measurements.

Managing soil salinity involves implementing various strategies to prevent or mitigate the negative effects of high salt levels. Some common techniques include:

  1. Proper irrigation management: Using irrigation methods that minimize water loss and salt accumulation, such as drip irrigation or sprinkler systems with good water distribution uniformity. Avoiding over-irrigation can prevent waterlogging and salt buildup.

  2. Improving soil drainage: Ensuring adequate drainage to prevent water stagnation and salt accumulation. Installing drainage systems, contouring the land, and incorporating organic matter can help improve soil drainage.

  3. Leaching excess salts: Applying additional water to the soil to flush out accumulated salts. This leaching process helps to move salts below the root zone and reduce their concentration in the active rooting zone.

  4. Selecting salt-tolerant crops and varieties: Planting crop species and varieties that are adapted to saline conditions can help minimize the negative impacts of soil salinity on plant growth and yield.

  5. Soil amendments: Using soil amendments like gypsum (calcium sulfate) to displace sodium ions and improve soil structure, which can enhance leaching efficiency and reduce soil salinity.

  6. Managing fertilizers: Carefully selecting and applying fertilizers to minimize the salt load added to the soil. Using fertilizers with lower salt content or adopting precision nutrient management techniques can help reduce the contribution of salts to the soil.

It is important to monitor soil salinity regularly through soil testing and analysis to assess its level and make informed management decisions. Understanding the causes and effects of soil salinity is crucial for maintaining soil health and productivity in affected areas.

Soil Conductivity

Soil conductivity refers to the ability of the soil to conduct an electrical current. It is a measure of the soil’s electrical conductivity (EC) and provides an indication of the concentration of ions, particularly salts, present in the soil solution. Soil conductivity is closely related to soil salinity, as higher salt concentrations result in increased electrical conductivity.

Soil conductivity is typically measured using a conductivity meter or probe, which measures the electrical conductivity of a soil sample or the soil solution extracted from the soil. The measurement is expressed in units of deciSiemens per meter (dS/m) or milliSiemens per meter (mS/m).

The electrical conductivity of soil is influenced by several factors, including the presence of dissolved salts, moisture content, temperature, and soil texture. Soil conductivity can vary widely depending on these factors, ranging from very low conductivity in soils with low salt concentrations to high conductivity in soils with high salt concentrations.

Monitoring soil conductivity is important for assessing soil salinity levels and understanding the potential impacts on plant growth and agricultural productivity. Excessive soil conductivity can indicate high salt concentrations, which can lead to reduced water availability for plants, nutrient imbalances, and impaired plant growth.

Soil conductivity measurements can be used to identify areas of the field that may have elevated salt levels, determine the effectiveness of drainage and leaching practices, and guide irrigation management decisions. By monitoring changes in soil conductivity over time, it is possible to evaluate the effectiveness of soil salinity management strategies and make adjustments as needed.

It’s worth noting that soil conductivity measurements provide an estimate of the overall salinity of the soil, but they do not provide specific information about the types and concentrations of individual salts present. For a more detailed analysis of soil salinity, additional laboratory testing, such as ion-specific analysis, may be required.

Overall, soil conductivity is a useful tool for assessing soil salinity and monitoring changes in salt concentrations over time. It helps guide management decisions to mitigate the negative impacts of soil salinity on plant growth and maintain soil health and productivity.

Soil Ion Exchange Capacity

Soil ion exchange capacity (CEC) is a measure of the soil’s ability to retain and exchange cations (positively charged ions) within its structure. It quantifies the soil’s capacity to hold and release essential nutrients for plant uptake. CEC is an important soil property that influences nutrient availability, soil fertility, and the soil’s ability to buffer against changes in pH.

Soil particles, particularly clay and organic matter, have negatively charged surfaces. These negative charges attract and hold cations, allowing for exchange with the soil solution. Common cations found in the soil solution include calcium (Ca2+), magnesium (Mg2+), potassium (K+), sodium (Na+), and hydrogen (H+).

The CEC of a soil is determined by the total number of negatively charged sites available for ion exchange. It is typically expressed in units of centimoles of positive charge per kilogram of soil (cmol/kg or cmolc/kg) or milliequivalents per 100 grams of soil (meq/100g). The higher the CEC value, the greater the soil’s ability to hold and exchange cations.

The CEC value of a soil depends on several factors, including the type and amount of clay minerals, organic matter content, soil pH, and the presence of other soil constituents. Soils with higher clay and organic matter content generally have higher CEC values due to the greater number of negatively charged sites available for cation exchange.

The significance of CEC lies in its role in nutrient availability. Cations such as calcium, magnesium, and potassium are essential for plant growth and are typically held on the exchange sites of the soil. As plants remove these nutrients from the soil, they are replaced through the process of ion exchange with other cations in the soil solution. CEC helps to retain and supply these nutrients to plants over time, reducing the risk of nutrient leaching and ensuring their availability for plant uptake.

In addition to nutrient availability, CEC also influences soil pH. The exchange of hydrogen ions (H+) on the soil’s exchange sites can impact soil acidity or alkalinity. Soils with high CEC have a greater capacity to resist changes in pH, as they can adsorb and release hydrogen ions.

Understanding the CEC of a soil is important for soil fertility management and nutrient recommendations. Soils with low CEC may require more frequent nutrient applications, while soils with high CEC may require adjustments to fertilizer rates or application timings to ensure optimal nutrient availability for plant uptake.

Soil testing and analysis are commonly used to determine the CEC of a soil. This information, along with other soil properties and nutrient levels, helps guide nutrient management practices, fertilizer application rates, and soil amendment decisions to maintain soil fertility and support healthy plant growth.

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