Course Content
Introduction to Environmental Chemistry
Environmental chemistry is the study of the chemical and biochemical phenomena that occur in nature. It involves the understanding of how the uncontaminated environment works, and which naturally occurring chemicals are present, in what concentrations and with what effects. Environmental chemistry; is the study of sources, reactions, transport, effects and fate of chemical species in water, soil and air environment as well as their effects on human health and natural environment
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Origin of the solar System
Cosmology; is the branch of astronomy involving the study of the of the universe and the solar system. Cosmo-chemistry ;( chemical cosmology); is the study of chemical composition of the matter in the universe and the process that led to those compositions The solar system is made up of the sun (a star) with nine planets orbiting around it. These planets together with all the other heavenly bodies moving around or between individual planet form members of the solar system. Other heavenly body include; asteroids, comets, meteors, meteorites and satellites such as moon. The solar system does not include other stars .
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Solutions
Solutions are defined as homogeneous mixtures that are mixed so thoroughly that neither component can be observed independently of the other. The major component of the solution is called solvent, and the minor component(s) are called solute.
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Chemical Equilibria
Chemical equilibrium in the environment refers to the state where the rates of forward and reverse reactions of a chemical reaction reach a balance. In this state, the concentrations of reactants and products remain constant over time, although the reactions continue to occur.
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Phase Interactions
Phase interactions in solutions refer to the behavior and changes that occur when two or more substances (solutes and solvents) mix together to form a homogeneous mixture. These interactions are related to the different phases of matter, such as solids, liquids, and gases, and how they interact and transform during the process of solution formation.
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Colligative Properties of Solutions
COLLIGATIVE PROPERTIES OF SOLUTIONS Colligative properties are physical properties of solutions that depend on the concentration of solute particles, rather than the specific identity of the solute. The four colligative properties that can be exhibited by a solution are: 1.Boiling point elevation 2.Freezing point depression 3.Relative lowering of vapour pressure 4.Osmotic pressure
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Introduction To Organic Chemistry
Organic chemistry is the study of carbon containing compounds and their properties. This includes the great majority of chemical compounds on the planet, but some substances such as carbonates and oxides of carbon are considered to be inorganic substances even though they contain carbon.
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Air Quality and Pollution
Air Quality and Pollution
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Introduction To Environmental Chemistry
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Simple Organic Molecules in the Environment

There are several common organic pollutants that can be found in the environment. Here are a few examples:

  1. Polycyclic aromatic hydrocarbons (PAHs): These are a group of chemicals that are formed during the incomplete burning of coal, oil, gas, wood, and other organic substances. PAHs can be found in air, soil, water, and even some food products.
  2. Volatile organic compounds (VOCs): VOCs are a wide range of carbon-based chemicals that can easily evaporate into the air at room temperature. They are often found in products such as paints, solvents, cleaning agents, and fuels. VOCs can contribute to air pollution and can have detrimental effects on human health.
  3. Pesticides:Pesticides are chemicals used to control pests, such as insects, weeds, and fungi. They can contaminate soil, water sources, and food. Pesticides include various organic compounds, such as organochlorines (e.g., DDT), organophosphates, and herbicides like glyphosate.
  4. Chlorofluorocarbons (CFCs)are a class of synthetic organic compounds that contain carbon, chlorine, and fluorine atoms. They were commonly used in various industries and products for several decades. CFCs gained popularity due to their stability, non-flammability, and non-toxicity.

One of the most significant applications of CFCs was as refrigerants in air conditioning and refrigeration systems. They were also used as propellants in aerosol products, blowing agents in foam production, and as solvents in various industrial processes.

However, CFCs have been identified as major contributors to ozone depletion in the Earth’s upper atmosphere. When released into the atmosphere, CFCs can rise to the stratosphere, where they are broken down by ultraviolet (UV) radiation. The breakdown of CFCs releases chlorine atoms, which can catalytically destroy ozone molecules. Ozone depletion leads to the thinning of the ozone layer, which plays a critical role in filtering out harmful UV radiation from the sun.

Due to the detrimental effects on the ozone layer, international agreements such as the Montreal Protocol have been established to phase out the production and use of CFCs. As a result, the use of CFCs has been significantly reduced, and alternative compounds with lower ozone depletion potential have been adopted.

The successful regulation of CFCs has led to a gradual recovery of the ozone layer, highlighting the importance of environmental policies and the global community’s efforts to address such environmental challenges.

  1. Hexachlorobenzene (HCB)is an organic compound composed of six chlorine atoms bonded to a benzene ring structure. It is a colorless solid that was historically used for various industrial purposes.

HCB was primarily used as a fungicide and as a chemical intermediate in the production of other chemicals. It has also been used as a wood preservative and in the manufacture of fireworks and dyes. However, its use has significantly decreased due to its persistence in the environment and its harmful effects.

HCB is considered a persistent organic pollutant (POP) because it does not easily break down in the environment and can accumulate in living organisms through the food chain. It can be released into the environment through industrial processes, waste incineration, and the use of HCB-containing products.

Exposure to HCB can have adverse effects on both human health and the environment. It is classified as a possible human carcinogen, meaning it may have the potential to cause cancer. HCB can also impact the liver, kidneys, and nervous system. In the environment, HCB is toxic to aquatic organisms and can bioaccumulate in fish and other wildlife.

  1. Polychlorinated dibenzo-p-dioxins (PCDDs)are a group of toxic organic compounds that are formed unintentionally as byproducts of certain industrial processes, combustion, and some natural sources. They belong to a larger family of chemicals known as dioxins, which include polychlorinated dibenzofurans (PCDFs) as well.

PCDDs are characterized by their chemical structure, which consists of two benzene rings connected by two oxygen atoms in a dioxin ring. Chlorine atoms are attached to different positions on the benzene rings, resulting in various forms or congeners of PCDDs with different levels of toxicity.

These compounds are persistent organic pollutants (POPs) that are resistant to degradation and can bioaccumulate in the environment and in living organisms. They are highly toxic and can have adverse effects on both human health and the environment.

Exposure to PCDDs usually occurs through the consumption of contaminated food, particularly animal-based products like meat, dairy, and fish. PCDDs can enter the food chain through environmental contamination, such as industrial emissions, waste incineration, and certain agricultural practices.

The health effects of PCDD exposure depend on the specific congener and the level and duration of exposure. PCDDs are known to be carcinogenic and can also have detrimental effects on the immune system, reproductive system, and hormone regulation. They have been associated with developmental abnormalities, reproductive disorders, and other adverse health outcomes in humans and animals.

Recognizing the risks associated with PCDDs and other dioxins, international efforts have been made to reduce their production and release. The Stockholm Convention on Persistent Organic Pollutants aims to minimize the release of PCDDs and other dioxins into the environment and promote their safe management and disposal.

Strict regulations on industrial processes, waste management, and monitoring of food and environmental samples help control the levels of PCDDs and protect human health and the environment from their harmful effects.

  1. Halonsare a class of organic compounds that contain bromine and other halogens (such as chlorine or fluorine). They were widely used as fire-extinguishing agents due to their effectiveness in suppressing fires. Halons were particularly valued for their ability to extinguish fires without leaving behind a residue or causing damage to sensitive equipment.

There are different types of halons, classified by their specific chemical composition. The most commonly used halons were halon-1211 (bromochlorodifluoromethane) and halon-1301 (bromotrifluoromethane).

While halons were highly effective in fire suppression, they were found to have significant environmental impacts. Halons are considered ozone-depleting substances (ODS), meaning they have the potential to contribute to the depletion of the ozone layer in the upper atmosphere.

The bromine atoms in halons are released into the atmosphere when they are used. These bromine atoms can catalytically destroy ozone molecules, leading to the thinning of the ozone layer. The depletion of the ozone layer allows more harmful ultraviolet (UV) radiation from the sun to reach the Earth’s surface, posing risks to human health and the environment.

Due to their detrimental impact on the ozone layer, the production and use of most halons have been phased out or significantly restricted under international agreements like the Montreal Protocol. The Montreal Protocol aims to protect the ozone layer by controlling and eliminating the production and consumption of substances that contribute to ozone depletion.

Today, alternative fire suppression systems and agents, such as halon substitutes, have been developed and adopted to minimize the use of halons while maintaining fire safety. These alternatives are designed to be less harmful to the ozone layer and have reduced environmental impacts.

The regulation and reduction of halon use demonstrate the global commitment to environmental protection and the preservation of the ozone layer, which is crucial for maintaining a sustainable and healthy planet.

Other  examples of simple organic pollutants commonly found in the environment:

  1. Benzene: Benzene is a colorless liquid with a sweet odor. It is released from various sources such as gasoline, emissions from vehicles, and industrial processes. Benzene is a known carcinogen and can contaminate air and water sources.
  2. Toluene: Toluene is a solvent commonly used in paints, coatings, and industrial processes. It is also found in gasoline. Exposure to toluene can cause neurological effects and respiratory irritation.
  3. Xylene: Xylene is another solvent used in many industrial applications, paints, and cleaning agents. It can be released into the air and contaminate water sources. Xylene exposure can lead to health issues such as headaches, dizziness, and respiratory problems.
  4. Trichloroethylene (TCE): TCE is a volatile organic compound (VOC) used as a solvent in industrial processes and as a degreaser. It can contaminate soil and groundwater. Prolonged exposure to TCE can cause health problems, including liver and kidney damage.
  5. Formaldehyde:Formaldehyde is a colorless gas with a strong odor. It is commonly used in the production of resins, plastics, and building materials. Formaldehyde can be emitted from these materials and can also be found in some household products. It is a respiratory irritant and a known carcinogen.

These are just a few examples of simple organic pollutants found in the environment. It’s important to monitor and regulate their release to minimize their impact on both environmental and human health.


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