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Heat and Changes of State
The discussion above and the accompanying equation (Q = m•C•∆T) relates the heat gained or lost by an object to the resulting temperature changes of that object. As we have learned, sometimes heat is gained or lost but there is no temperature change. This is the case when the substance is undergoing a state change. So now we must investigate the mathematics related to changes in state and the quantity of heat.
To begin the discussion, let’s consider the various state changes that could be observed for a sample of matter. The table below lists several state changes and identifies the name commonly associated with each process.
Process |
Change of State |
Melting |
Solid to Liquid |
Freezing |
Liquid to Solid |
Vaporization |
Liquid to Gas |
Condensation |
Gas to Liquid |
Sublimation |
Solid to Gas |
Deposition |
Gas to Solid |
In the case of melting, boiling and sublimation, energy would have to be added to the sample of matter in order to cause the change of state. Such state changes are referred to as being endothermic. Freezing, condensation and deposition are exothermic; energy is released by the sample of matter when these state changes occur. So one might notice that a sample of ice (solid water) undergoes melting when it is placed on or near a burner.
When heat is transferred from the burner to the sample of ice; energy is gained by the ice causing the change of state. But how much energy would be required to cause such a change of state?
The amount of energy required to change the state of a sample of matter depends on three things.
- It depends upon what the substance is,
- on how much substance is undergoing the state change, and
- upon what state change that is occurring.
For instance, it requires a different amount of energy to melt ice (solid water) compared to melting iron. And it requires a different amount of energy to melt ice (solid water) as it does to vaporize the same amount of liquid water. And finally, it requires a different amount of energy to melt 10.0 grams of ice compared to melting 100.0 grams of ice.
The substance, the process and the amount of substance are the three variables that affect the amount of energy required to cause a specific change in state.
The values for the specific heat of fusion and the specific heat of vaporization are reported on a per amount basis. For instance, the specific heat of fusion of water is 333 J/gram. It takes 333 J of energy to melt 1.0 gram of ice. It takes 10 times as much energy – 3330 J – to melt 10.0 grams of ice. Reasoning in this manner leads to the following formulae relating the quantity of heat to the mass of the substance and the heat of fusion and vaporization.
For melting and freezing: Q = m•ΔHfusion
For vaporization and condensation: Q = m•ΔHvaporization
Where
Q represents the quantity of energy gained or released during the process,
m represents the mass of the sample,
ΔHfusion represents the specific heat of fusion (on a per gram basis) and
ΔHvaporization represents the specific heat of vaporization (on a per gram basis).
Similar to the discussion regarding Q = m•C•ΔT, the values of Q can be either positive or negative. Values of Q are positive for the melting and vaporization process; this is consistent with the fact that the sample of matter must gain energy in order to melt or vaporize. Values of Q are negative for the freezing and condensation process; this is consistent with the fact that the sample of matter must lose energy in order to freeze or condense.
As an illustration of how these equations can be used, consider the following two example problems.
Example Problem 3
Elise places 48.2 grams of ice in her beverage. What quantity of energy would be absorbed by the ice (and released by the beverage) during the melting process? The heat of fusion of water is 333 J/g.
The equation relating the mass (48.2 grams), the heat of fusion (333 J/g), and the quantity of energy (Q) is Q = m•ΔHfusion. Substitution of known values into the equation leads to the answer.
Q = m•ΔHfusion = (48.2 g)•(333 J/g)
Q = 16050.6 J
Q = 1.61 x 104 J = 16.1 kJ (rounded to three significant digits)
Example Problem 3 involves a rather straightforward, plug-and-chug type calculation. Now we will try Example Problem 4, which will require a significant deeper level of analysis.
Example Problem 4
What is the minimum amount of liquid water at 26.5 degrees that would be required to completely melt 50.0 grams of ice? The specific heat capacity of liquid water is 4.18 J/g/°C and the specific heat of fusion of ice is 333 J/g.
In this problem, the ice is melting and the liquid water is cooling down. Energy is being transferred from the liquid to the solid. To melt the solid ice, 333 J of energy must be transferred for every gram of ice. This transfer of energy from the liquid water to the ice will cool the liquid down. But the liquid can only cool as low as 0°C – the freezing point of the water. At this temperature the liquid will begin to solidify (freeze) and the ice will not completely melt.
We know the following about the ice and the liquid water:
Given Info about Ice:
m = 50.0 g
ΔHfusion = 333 J/g
Given Info about Liquid Water:
C = 4.18 J/g/°C
Tinitial = 26.5°C
Tfinal = 0.0°C
ΔT = -26.5°C (Tfinal – Tinitial )
The energy gained by the ice is equal to the energy lost from the water.
Qice = -Qliquid water
The – sign indicates that the one object gains energy and the other object loses energy. We can calculate the left side of the above equation as follows:
Qice = m•ΔHfusion = (50.0 g)•(333 J/g)
Qice = 16650 J
Now we can set the right side of the equation equal to m•C•ΔT and begin to substitute in known values of C and ΔT in order to solve for the mass of the liquid water. The solution is:
16650 J = -Qliquid water
16650 J = -mliquid water•Cliquid water•ΔTliquid water
16650 J = -mliquid water•(4.18 J/g/°C)•(-26.5°C)
16650 J = -mliquid water•(-110.77 J/°C)
mliquid water = -(16650 J)/(-110.77 J/°C)
mliquid water = 150.311 g
mliquid water = 1.50×102 g (rounded to three significant digits)
Latent Heat:
Latent heat is the quantity of heat energy that is required to change a substance from one state to another at constant temperature and pressure. The unit of latent heat is Joule (J), and the symbol used for latent heat is Q. The quantity of heat that is required to change a substance from one state to another is directly proportional to the mass of the substance.
Mathematically:
- Quantity of heat energy ∞ mass of substance
- Q ∞ m
- Introducing the constant of proportionality: Q = L X m
- L is the constant of proportionality. It is called the specific latent heat of the substance.
- M is the mass of the substance measured in kilogram.
- Q is the quantity of heat measured in Joule.
Factors that determine the quantity of heat required to change the state of a substance:
The following factors determine the quantity of heat energy that is required to change a substance from one state to another:
- The nature of the substance.
- The mass of the substance.
- The quantity of energy supplied.
- The volume of the substance
- The area of the substance
- The state of the substance as the time the heat energy is supplied.
Specific Latent Heat of A Substance:
Specific latent heat of a substance is the quantity of heat energy that is required to change 1kg mass of the substance from one state to another at constant temperature.
Specific Latent Heat of Fusion of Ice:
Specific latent heat of fusion of ice is the quantity of heat energy that is required to change 1kg mass of ice block into liquid at constant temperature Or melting point of the ice block. It is a scalar quantity.
- Specific Latent Heat Of Fusion of Ice L ice = 336 J/g
- Formula Of Specific Latent Heat Of Fusion Of Ice:
- Quantity of Heat energy Q = mass of ice block * specific latent heat of ice block Q = mXLice
- Specific latent beat of ice Lice = Q/m
Examples:
- Calculate the quantity of heat energy that is required to change 25.6 kg mass of ice to liquid at constant temperature.
Solution:
- Mass of ice block m = 25.6 kg = 25.6 * 1000 = 25600g, Lice = 336J/g, Q = ?
- Formula: Q = m X Lice
- Substitution: Q = 25600 X 336
- Q = 8601600 Joules
- The quantity of heat that is required to change X g of ice to liquid is 235 J. If the Lice is 336J/g, calculate the mass of the object.
Solution:
- Mass = ?, Q = 235 J, Lice = 336J/g
- Formula: Q = m*Lice
- Substitution: 235 = m X 336
- Make m the subject: m = 235/336
- M = 0.699 g
Effect Of Expansion And Contraction On Fusion:
ü Glass bottle of water crack on freezing because water expands on freezing and because of unequal expansion of the bottle.
ü When water freezes into ice, it expands, become less dense and float on water with nine – tenth (9/10 ) of its volume submerged in water. Ice contracts on melting.
Effect Of Pressure on Freezing Point of a Substance:
- Increase in pressure lower the melting point of ice or the freezing point of water. This is called regelation of ice.
- An increase in pressure lowers the freezing point of any liquid which expands on solidifying. E.g water.
III. Increase in pressure increases the freezing point of any substance which contract on solidifying. Eg paraffin-wax.
Effect Of Impurities On Freezing Point Of Substance
The presence of impurities in a substance lower the melting point of pure substance
Specific Latent Heat Of Vaporization
Specific latent heat of vaporization of steam is the quantity of heat energy that is required to change 1kg mass of a liquid into steam / gas at constant temperature ( boiling point) and pressure. It is a scalar quantity. The unit of specific latent heat of vaporization of steam is J/Kg or J/g.
Relationship Between Specific Latent Heat Of Fusion Of Ice and Specific Latent Heat Of Vaporization Of Steam
Specific latent heat of fusion of ice Lice = 1/7 of specific latent heat of vaporization of steam
L ice = 1/7 X Lsteam
Example 1:
- If the latent heat of fusion of ice is 336J/g, what is e specific latent heat vaporization of steam?
- Specific latent heat of fusion of ice Lice = 336j/g.
- Lsteam = ?
specific latent heavy of fusion of ice Lice = 1 /7 Specific latent heat of steam
- Lice = 1/7 of Lsteam
- Substitution: 336 = 1/7 of Lsteam
- Make Lsteam the subject: Lsteam = 7*336
- Lsteam = 2352J/g
- What is the specific latent heat of fusion of ice if that of steam is 2352J/g?
Specific latent heat of vaporization of steam Lsteam = 2352J/g,
- Lice = ?
- Formula : Lice = 1/7 of L steam
- Substitution: L ice = 1/7 * 2352.
L ice = 336 J/g