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CRYOGENIC LIQUID STORAGE
Cryogenic liquids can be transported, stored, and handled in a variety of containers depending on quantity and desired use.
Dewar flasks
Dewar flasks are smaller, double-walled cryogenic storage containers that usually only maintain the liquid for a few hours. They usually have a metal outer wall and a glass inner wall, with the void space under high vacuum for maximum thermal insulation.
Special care should be taken when handling as these flasks can implode. They have a loose fitting insulated cap that enables gases to escape while preventing moisture buildup at the neck. In many cases they are used at “satellite” cryogenic liquid containers within a lab.
Dewar flasks are constructions or designed to minimize heat leaks into the refrigerants.
Heat can leak into the refrigerant by
(a) Thermal conduction down the material of the neck tube of the Dewar vessel
(b) Radiation of the outer shell to the inner shell of the Dewar vessel
Conduction through the residual gas between the two shells of the Dewar flask
To minimize heat loss due to thermal conduction, the neck tube of the Dewar is made long and of materials whose thermal conductivity is poor. Whereas to minimize heat lose by radiation, the surface of the two shells should be polished. Heat loses or leaks due to conduction by residual gas are normally reduced by using a multilayer vacuum insulation, which is referred to as supper insulation.
If any air is allowed to enter a Dewar vessel containing a cryogenic fluid, the air would solidify inside and as a result, these may cause a blockage of the neck tube (causes gas- plug ) and prevents the escape of boiled off gases. The gas –plug formed can be removed by directing a steam of room temperature helium gas down through the gas –plug so as to dislodge it.The Dewar flask
Cryogenic Liquid Cylinders
Cryogenic liquid cylinders, sometimes also referred to as Dewars, are insulated, vacuum jacketed, pressurized vessels. They come equipped with safety relief valves and rupture disks to alleviate pressure buildups. These cylinders come in a variety of sizes ranging from 80-450 liters. They can be equipped to provide gas through an internal vaporizer or provide liquid under their own internal vapor pressure. These cylinders are usually filled by the users at filling stations throughout the campus. All users must wear proper PPE when filling and discharging. Cryogenic cylinders routinely relieve their internal pressure and you may observe a sudden hissing sound and the appearance of a fog. This is completely normal. When using cryogenic cylinders, users should ensure that all valves and pressure relief devices are in place and in good condition. If pressure relief devices fail, catastrophic failure may result.
Cryogenic Liquid Cylinders
Cryogenic liquid cylinders, sometimes also referred to as Dewars, are insulated, vacuum jacketed, pressurized vessels. They come equipped with safety relief valves and rupture disks to alleviate pressure buildups. These cylinders come in a variety of sizes ranging from 80-450 liters. They can be equipped to provide gas through an internal vaporizer or provide liquid under their own internal vapor pressure. These cylinders are usually filled by the users at filling stations throughout the campus. All users must wear proper PPE when filling and discharging. Cryogenic cylinders routinely relieve their internal pressure and you may observe a sudden hissing sound and the appearance of a fog. This is completely normal. When using cryogenic cylinders, users should ensure that all valves and pressure relief devices are in place and in good condition. If pressure relief devices fail, catastrophic failure may result.
The Dewar flask
Storage of Cryogens
The storage of cryogens requires careful consideration and adherence to safety guidelines to ensure the integrity of the containers and the safety of the surrounding environment. Here are some key points to consider for the storage of cryogens:
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Dedicated Storage Areas: Cryogens should be stored in designated storage areas that are well-ventilated, well-lit, and away from sources of heat, ignition, or direct sunlight. These areas should be clearly marked and restricted to authorized personnel only.
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Appropriate Containers: Cryogens should be stored in containers specifically designed and approved for cryogenic storage. These containers are typically insulated and have pressure relief mechanisms to prevent excessive pressure buildup. The containers should be properly labeled with the name of the cryogen and any associated hazards.
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Compatibility and Segregation: Different cryogens may have incompatible properties or react with each other. Therefore, it is important to segregate cryogens based on their chemical properties to prevent potential reactions or contamination. Proper signage and labeling should be used to identify storage areas for specific cryogens.
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Ventilation: Adequate ventilation should be provided in cryogen storage areas to prevent the accumulation of gases or vapors. Ventilation systems should be designed to handle any potential leaks or releases of cryogenic gases.
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Temperature Monitoring: Cryogen storage areas should be equipped with temperature monitoring systems to ensure that the storage temperatures are maintained within the recommended ranges. Regular temperature checks and monitoring should be conducted to detect any deviations or abnormalities.
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Handling Precautions: Proper handling procedures should be followed when moving or transporting cryogens within the storage area. This may include the use of appropriate personal protective equipment (PPE), such as insulated gloves, face shields, and safety goggles, to protect against cold burns or inhalation hazards.
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Emergency Preparedness: Adequate emergency response plans should be in place, including procedures for handling spills, leaks, or accidents involving cryogens. Emergency equipment, such as eyewash stations, emergency showers, and spill control materials, should be readily available and regularly maintained.
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Training and Knowledge: All personnel involved in the storage and handling of cryogens should receive proper training on the properties, hazards, and safe practices associated with cryogenic materials. This includes training on proper storage procedures, handling techniques, and emergency response protocols.
It’s important to consult applicable regulations, safety guidelines, and best practices specific to your location and the type of cryogens being stored. Safety should always be the top priority when storing cryogens to prevent accidents, injuries, or environmental hazards.