Views: 55
The Periodic Trends
The elements on the periodic table are arranged periodically so that trends can be easily recognized. Trends run horizontally across the periodic table starting from the left hand-side to the right. For instance , from the period you can easily determine the following trends
- Trends of ionsg. group 1 elements have a +1 ionic charge whereas group two, three, four , five , six and seven have +2,+3,±4,-3,-2,-1 ionic charge respectively
- Trends of electronegativity
Another important periodic trend to be aware of is how electronegativity differences can be identified. Electronegativity is the measure of an atom’s tendency to attract a bonding pair of electrons. There are various numerical scales for rating electronegativity. The trends for electronegativity in the periodic table are that electronegativity increases as you go across a period, and increases as you go up a group, with fluorine being the most electronegative atom. Noble gases are given an electronegativity rating of 0 due to their inherent stability, which keeps them from forming bonds with other atoms.
3. Trends of electron affinity
this measures the tendency for an atom to gain electron . this is caused by the filling of the valency shell. The trend increases across the period and decreases down the group due the electron entering an orbit far away from the nucleus
4. Trend of ionization energy:
Another periodic trend that you will be expected to know is the trend for ionization energy. Ionization energy is defined as the amount of energy required to remove the most loosely bound electron of an atom. How tightly bound the electrons of an atom are will affect the amount of energy required to remove one of the valence electrons. Electrons that are closer to the nucleus are going to be more tightly held than those that are further away and will require more energy to pull them off of the atom. For this reason, we see that ionization energy decreases as you go down a family group and the atoms get larger. This same concept can be applied to atoms across a period. We will see that the highest ionization energy will be found on the right side of the period where the atoms are the smallest, and the lowest ionization energy on the left where the atoms have a larger radii. In general, ionization energy decreases as you go down a family group, and increases as you go across a period from left to right
6. Trend of atomic radius;
One important trend to be aware of is the way that atomic size changes as you move across a period or down a group in the periodic table. Atomic size is typically measured by the radius of the atom starting at the core of the nucleus, and reaching all the way out to the last valence electron.
As you may predict, atomic size will increase as you move down a family group, due to the increased number of electron shells. This substantially increases the size of the electron cloud. What you may not so easily predict is that atomic size decreases as you go across a period.
Although this may seem counter-intuitive, the decrease in size can be explained by thinking about the valence electron shell as you go across a period; we see that each element across a period has the same valence electron shell that it is filling with valence electrons. While the valence shell stays the same as you go across a period, the number of protons is increasing. Protons, being positively charged, have a pull on the negatively charged electrons out in the electron cloud.
As the number of protons and electrons increases across a period, they have an attractive pull on one another. This results in a tightening of the electron cloud and a reduction in the atomic nuclei. In other words, because the outermost electron shell remains the same across a period, that shell gets pulled progressively closer and closer to the nucleus of the atom as you go across a period. So the overall periodic trend for atomic radius (size) is that atoms get smaller as you go across a period, and they get larger as you go down a family group
8.Trends of metallic /nonmetallic properties.
Metallic character refers to the level of reactivity of a metal. Metals tend to lose electrons in chemical reactions, as indicated by their low ionization energies. Within a compound, metal atoms have relatively low attraction for electrons, as indicated by their low electronegativities. By following the trend summary in the figure below, you can see that the most reactive metals would reside in the lower left portion of the periodic table. The most reactive metal is cesium, which is not found in nature as a free element. It reacts explosively with water and will ignite spontaneously in air. Francium is below cesium in the alkali metal group, but is so rare that most of its properties have never been observed.
The metallic character increases as you go down a group. Since the ionization energy decreases going down a group (or increases going up a group), the increased ability for metals lower in a group to lose electrons makes them more reactive. In addition, the atomic radius increases going down a group, placing the outer electrons further away from the nucleus and making that electron less attracted by the nucleus.
Nonmetals tend to gain electrons in chemical reactions and have a high attraction for electrons within a compound. These tendencies are known as nonmetallic character. The most reactive nonmetals reside in the upper right portion of the periodic table. Since the noble gases are a special group because of their lack of reactivity, the element fluorine is the most reactive nonmetal. It is not found in nature as a free element. Fluorine gas reacts explosively with many other elements and compounds and is considered to be one of the most dangerous known substances.
Note that there is no clear division between metallic and nonmetallic character. As we move across the periodic table, there is an increasing tendency to accept electrons (nonmetallic) and a decrease in the possibility that an atom would give up one or more electrons
9. Trends of melting and boiling points:
Melting and boiling points increases from the right of the periodic table until it reaches aluminum and silicon when melting point and boiling point again begin to decrease.
10. Trends in reactivity:
Reactivity refers to how likely or vigorously an atom is to react with other substances
For metals, reactivity decreases from left to right across the period and increases down from top to bottom of the group.
For non-metals, the reactivity increases from left to right across the period and decreases down the group
An illustration showing Summary of Major Periodic Trends